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La2Ga5SiO14 (Langasite) - Main Applications
LanGaSite
Lanthanum gallium silicate crystal (langasite - LGS) was first grown in Russia at the beginning of the 1980?s, as a result of joint development of the Moscow State University (MGU) and the Institute of Crystallography of the Russian Academy of Sciences. Initially this crystal was intended for use in laser engineering but for a number of reasons it did not find a suitable application in this area. The profound research of the physical properties of langasite carried out by the Institute of Crystallography revealed its piezoelectric characteristics, which predetermined the use of langasite in piezoelectrical engineering.
The sphere of piezoelectrical engineering embraces radio frequency control elements (resonators) and selection devices (filters). The predominant material used for this purpose is quartz, which possesses highly stable frequency and temperature characteristics. However the use of quartz in piezoelectric filters is quite limited because its index of electromechanical coupling K²el.mech is very low and averages about 7%. This quality confines the use of quartz to narrow band filters with the relative value of the pass band to the centre frequency up to 0.3%.
Present-day digital methods of signal treatment require a broader pass band in intermediate frequency amplifiers. To produce such filters with quartz it is necessary to install additional elements (e.g. inductive coils), which increases the size and weight of the gadget. The alternative solution is the use of a piezoelectric material with a higher K2el.mech. value.
A suitable mateial for broad band filters is lithium tantalate. The relative pass band of the filters based on lithium tantalate lies in the range of 0.6 ? 4 %. However the frequency-temperature stability and the quality (Q-factor) of such filters remain quite low, hampering their unanimous promotion. An ideal crystal for a filter with a relative pass band 0.3-0.8% should have properties intermediate between those of quartz and lithium tantalate. The best solution to this problem is langasite. Langasite-based filters possess relative pass band between 0.3-0.85%. Besides, langasite is a perfect material for resonators with 0.8% resonance required in new types of oscillators.
The most promising application of langasite crystal is piezoelectric substrates for filters operating both at bulk waves (BAW) and surface waves (SAW).
The basic piezoelectric properties of different crystals operating at bulk waves are represented and compared in Chart 1. The chart shows that all the main characteristics of langasite, such as index of electromechanical coupling, frequency, Q-factor and temperature-frequency coefficient are intermediate between those of quartz and lithium tantalate.
Chart 1. Comparison of the basic properties of piezoelectric crystals
     
Crystals Index of el.mech. coupling Kemc, %Frequency spacing deltaf, %Q-factor Q, x10³ Temperature frequency coefficient, TFC, x10-1C?
Quartz, SiO2 7.00.251000.5
Langasite, La3Ga5SiO14 15.80.90501.6
Lithium-tetraborate, Li2B2O3 24.04.00106.0
Lithium-tantalate, LiTaO3 47.07.0024.0
Langasite BAW filters are highly competitive compared with analogous quartz filters. The design of this type of filter is patented.

The use of langasite crystals for surface acoustic wave (SAW) filters is quite perspective in view of the rapid development of mobile telephony. The telephones of new standards (W-CDMA) open up new opportunities of information transfer. The basic characteristics of LGS crystals for surface acoustic waves are represented in Chart 2.
Chart 2. Comparison of surface waves in quartz and LGS crystals
    
Characteristics Quartz, SiO2LGS, La3Ga5SiO14 
Vef
SAW velocity
0?, 132.75?, 0?
3157
0?, 140?, 22.5?
2742
0?, 140?, 25?
2736
K2emc 0,140,320,38
a2 x 108/?C2 -3.2-7.8-6.8
TT,?C (temp. coef.) 252523
E (dielectric constant) 4,92-27
M, degr. (power flow angle) 05251
The chart shows that the K2el.mech. value of LGS crystals is twice as big as that of quartz, while the temperature coefficients of the two crystals are equal. These qualities of langasite make it possible to manufacture broad band filters with high temperature stability. Another important parameter is the value of propagation velocity, which determines the size of the filter. The lower this figure is, the smaller is the filter, which is very important for the present-day market of electronic devices. It is clear from the chart that the propagation velocity of langasite-based SAW filters is considerably lower, thus the filters can be as tiny as required for the modern small-sized gadgets.
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